Dont know if this will be any help to those who cant initiate their quicksilver missions, but from my experience you have to reconnect to the internet right after disconnecting (while the game is running), i.e. hit disconnect and connect right after the button becomes available.
Looking closely at the discovery page, it seems to, obviously in error, report online discovery services being back online at the instant the internet is disconnected! Then once the connection is re-established, it either stays green for a few momments, goes blue (connecting) or red (connection lost) right away.
Because the duration of this burst of connectivity is random and potentially very brief, as others have mentioned, it is best to already be standing in front of the Nexus before attempting the trick.
TL;DR:
1) Stand in front of the Nexus.
2) Alt-Tab and disconnect from the internet.
3) Re-connect as soon as the button becomes available.
4) Alt-Tab back to the game and wait for the QS mission to pop-up.