gnarbrag: NWN2: Storm of Zehir allows you to make your own party (of 4 characters) similar to IWD and BG
This is more sandbox than story. It's my least favorite of all the original campaigns or expansions.
I had a hard time dragging through the tedium to complete it, where I played everything else multiple times.
I would not recommend it as a start, or at all really.
I would echo the recommendation of the first reply. Start with the original campaigns.
I would say start with NWN 1, so do the kind of lame Prelude/tutorial. This OC is considered fairly weak, but it gets dumped on a bit overmuch. It's mainly the Prelude/Ch1 that are weakest, Ch2/Ch3 are not bad at all.