Lots of good mentions thus far, but it's lacking a big one. I've seen quite a bit of pixel art and the best I've seen by far on GOG is in
Rain World. That game is beautiful purely on its own merits and a fantastic execution of pixel art as a graphical style - no need for nostalgia goggles.
Anyone interested should watch a video first because the screenshots do not do justice to how it looks in motion. Also, keep in mind that it's a challenging game that plays by its own rules. You'll get frustrated if you try to approach it as a typical platformer, but if you can get past that and play it on own terms you'll be getting a rather special experience in return.
By which I mean to say that it's quite good, in case that wasn't clear.