piranha1: Does the White March add a new story at the end of the basic game (like an expansion, e.g. Throne of Bhaal for Baldur's Gate 2)
It adds more content for the basic game before the ending (like an expansion, e.g. Tales of the Sword Coast for Baldur's Gate :-P)
Entire White March (pt. 1 and 2) adds between 25-30 hours of content set in an entirely new region + 2 new locations to the map of the base game. It rises the level cap to lvl 16 and allows you to choose whether you want the third act of the base game to be more difficult to compensate. It also adds a new type of items called "Soulbound" which can be bound to characters with certain classes and then level up and gain new abilitities - so that's to the extent of that, whether you call it expansion pack or DLC is up to you.
Anyway, if you're worried about having to replay the game, you don't - as long as you held onto your old saves. The original Pillars of Eternity has automatically created a hard save before you enter the point of no return in the epilogue, and if you wish, you can load that save and use your party from it. Upon entering White March, you'll be asked whether you'd like the expansion to be switched to a mode for lvl12 characters.