mna99: Glad you noticed that, and I can't emphasize enough how potent that is if you have your party set up the right way.
Everyone who is a front-liner needs Opportunist and Combat Reflexes/Seize the Moment. Then get them an 18-20 crit range weapon appropriate to their role, and finally get Improved Critical for that weapon (or just make sure to get a +5 Keen one if one is available). Possible exception: Valerie. It's still useful for her to have those feats, but if you are running her as a straight-up tank, giving her a critfest weapon is a secondary priority vs. stuff like Mallet of Woe.
@mna99 Please refrain from spreading your confusion to others. Outflank, not Opportunist. Opportunist is a rogue talent and it's not a teamwork feat - it's not something 'everyone who is a front-liner needs' or can even attain.
Also, Seize the Moment isn't a good fit for many heavy armored front-liner types (like Valerie), as it has Combat Reflexes for a prereq, which doesn't make sense to grab unless you have DEX modifier of at least +2.
For most 'front-liners' Outflank will do the job (it also has another benefit like adding +4 AB...) - Keep it simple and don't hurt yourself; Outflank is the teamwork feat you want all melee types to grab.