ChewyWeAreNotHome: This is something that is associated with the changes made for Vulkan months ago. GOG support staff tried to help me for a couple of weeks and finally had to throw in the towel as this appears to be a programming issue as NMS has these keys assigned to other game controls.
See
https://www.gog.com/forum/no_mans_sky/galaxy_overlay_after_vulkan_177_vulkan I rather blame GoG, cause Valve and EA managed to get their overlays working in Vulkan games, regardless if those games have the same bindings as the overlay (being Valve the best example with their own games).
Adding to that, the Steam Overlay is working fine on NMS Steam Release, which proves my point further.
If this was a problem with the game and Vulkan itself, it would impact Steam as well, GoG that needs to work on their overlay to fix compatibility (they can't expect the developers to waste time and resources on a feature they not responsible for).
I mean if you look closely, the GoG GALAXY overlay doesn't work in the majorly of games, even with CD PROJEKT own games there's problems (The Witcher 3).
I personally never saw the GoG GALAXY overlay once, and yes I have it enabled and it never worked in any game (as I said before, not even The Witcher 3).