thme: I am playing a paladin in the first scenario (level 3) and I have read that taking 4 levels of fighter would be beneficial. When do I take these, is there a particular schedule? Also, is there another class that would multi-class well? I am curious about what other multiclass combinations work well.
Yes, FTR levels work very well, as you get 3 extra feats for 4 levels. This allows you to grab Weapon Specialization for the +2 damage bonus with your weapon of choice. You can take them whenever you want. Generally it's done relatively early in order to cash in on the bonus feats early though.
Other classes that mix well with Paladin are Champion of Torm, Monk (depending on how you build the character) and, to a lesser extent, Sorcerer (add some Red Dragon Disciple for the stat boosts and you can build a pretty kick ass character). Another one I love to mix with Paladin is Rogue, but many people take issue with that from a roleplay perspective (I don't).