ArbitraryWater: I bought both around the same time when I originally got them, and VI is the objectively better of the two, considering it's about twice as long (60+ hours), and therefore allows for a longer, more epic adventure. However, VII is a more streamlined and polished game. It allows for more variety in party creation, it doesn't contain those hilarious/embarrassing digitized character portraits, and is generally easier.
You should probably start with VI, but if you have trouble you should maybe try out VII first. After that, VIII is probably the next logical step, followed by III or Xeen. I think VIII is alright, even if the fact that it was made in a year is
painfully obvious throughout, and the difficulty is super imbalanced thanks to the presence of dragons as party members, who basically allow you to steamroll through the game no problem whatsoever. It's actually kind of sad.
VIII has some fantastic art work however... I would love to extract the art displayed while loading a game or an area and set some of them as background!!!!