ChaunceyK: I found out about GOG while browsing an abandonware site, Home of the Underdogs, and I saw a banner ad for GOG. The good thing about the HotU site I was on (it had splintered into a few sites for reasons I never cared to learn) was that the moment they discovered a game was being offered for digital download, they'd remove it from their site...they'd leave up all the info about & the game, but they'd say "This game is available for purchase at [insert DD sites here]." I thought that was pretty classy.
HOTU=best site ever, I plan to slowly replace my "abandonware" collection with gog downloads as they are released ;)
On topic, for me it was Planescape Torment, it was never on sale here in Serbia and my relatives in germany were never able to get it for me, it will be my next purchase on gog :)