JMich: Just as amok replied, Steam has an agreement with Sega, which also includes the rights to use a Mega Drive emulator. GOG.com doesn't have (yet) a contract with Sega, so it can't sell any Sega game, nor a Sega emulator. Hopefully, that will change in the future, even if I don't particularly care that much about the console games.
yes, but also that each single SMD game SEGA sells it packed with the emulator. SEGA can do this easily as they are the distributors / owners of the game, the OS, and the proprietary emulator software (and there really is no reason why it is not on Gog yet...)
PS is a different kettle of fish, there is no proprietary emulator, and all the exiting ones are in a very legal grey area, and Sony often do not have the rights to the game so any deals must be done with each rights owner. Making one would cost Sony some development and research time + money, which they might not feel is worth doing.
If there for some reason becomes available a third party legal emulator, then it becomes a matter of costs and how it is handled. Do each game come with the emulator? This will drive up the cost, as there will be additional costs for each game sold. Should you need to buy the emulator and then the games separately? this will keep the cost of the actual games down, but then they will no longer be able to play out of the box, with all the problems goG will get steaming out from this.
Lastly, can not the game "just be ported by Gog?", no, not really. Even if it was technically possible to port the games, you will need access to source codes and the rights to alter them. AFAIK GoG do not have access to any source codes of any games they sell, and they do not have the rights to alter any game they sell either (except maybe the Witcher games, not sure how legalities are handled with CDRed...), so goG can not do anything at all with the original code. This then need to be handled by rights owners (
Acquire I think it is), so if you want a port to PC which GOG can distribute, you would need to plea with them.
wall of text... TL:DR, it is not as easy as it might seem....