The Wikipedia article on Ludwig II (at
https://en.wikipedia.org/wiki/Ludwig_II_of_Bavaria) suggests that he was homosexual based on diary entries and letters dating back to the 1860s, but does not provide a link to those letters; take that with as much salt as you like, or do your own research on Ludwig II.
As for the Royal Bavarian Hunting Lodge, well, it is an exclusive men's club, which would of course attract men who prefer the company of other men to that of women. That is not to say that any given member necessarily does.
The only club members whose sexuality can be easily inferred are Gabriel (straight), Von Glower (either bi or gay, depending on whether he really liked that woman who was with him or was just pretending to), and Preiss, who talks a big talk about liking women (straight), but brought his bondage gear with him on the hunting trip, even though he had very little chance of using it on women. (Or men, for that matter, given what everyone else in the club thinks about him.)
Von Zell may have had a sexual attraction to Von Glower independent of the werewolf bond, or maybe his possessiveness had nothing to do with anything except the werewolf bond. (Von Glower is MY alpha werewolf, and I won't share him with any other beta!)