I am trying to use Yoanna as the master armourer to craft Wolven gear, but Superior gear doesn't show up:( It even shows Mastercrafted but not Superior.

Anyone know how to fix this? Or is there a debug console I can download?

To craft each tier of Witcher armour you NEED the level below it as the base. So to craft Superior, you need to have the Enhanced version in your inventory. The armour is actually upgraded, not crafted from new.