Tech is better for throwing because of the wide variety of grenades and explosives you have access to if you go tech. ALso, with an Apprentice in throwing, you can throw an infinite number of grenades without spending action points. As mentioned earlier, the grenadier build in Arcanum is OP.
That being said, and whichever path you go - Get the Aerial Decapitator
https://arcanum.fandom.com/wiki/Old_Blind_Master The location will not be marked on your map, and you won't be able to reach him until after the Dredge. But once you do - you have access to not only the Best Throwing Weapon, but also one of the best weapons in the game, period. Whether you go a mage build that grants you access to useful spells (heal, jolt, etc), or a tech build thjat allows you to craft all the explosives you need, whatever the case, the aerial decapitator, being a neutral weapon, is THE weapon to get for a true throwing master.
One thing that would give a mage character an advantage - temporal spells like hasten and tempus fugit. Grenades are badass, but, they are limited, and you have to keep crafting them. In contrast, a mage character with haste and tempus fugit, along with the aerial decapitator, can keep delivering crits within the first phase.
A potential optimum would be a technomage, now that I think about it - Half-elf, 10 tech schematics (all explosives, with 3 in any schematics of your choosing) and 10 mage skills (temporal, and the other can be something like conveyance or force) and of course, the aerial decapitator. I'll have to give that build a try sometime
TwoHandedSword: The best throwing weapon in the game, whose quest you get from the Throwing master, works best if you're magically inclined.
Its decent. While Azrams star is good as a throwing weapon, a magical throwing weapon that is - by the time you can reach that location, you can also go to the blind master house by then, and get the REAL best throwing weapon imho. The only real drawback to the Aerial Decpitator is the lack of range but, as a close range throwing weapon, its damage far surpasses any others in the game. That said, and looking at the stats, the azrams star can be thrown further, and has a faster speed. I guess its up to preference.