I'm only going to comment on which ones are the worst on my personal GOG shelf (and of the games I've actually played)...no idea whether or not a game like Kingdom: The Far Reaches is if I haven't ever played it.
Shelf: [url=http://www.gogwiki.com/wiki/User:DProject]http://www.gogwiki.com/wiki/User:DProject[/url]
Starting off with a game that will surely get some disagreement from folks over here: The Last Express. The idea of the game is alright, but I found the execution too complex. I felt that many key elements in the plot could only be found on an odd chance. It was almost always unclear, where you needed to be and what you needed to do. I've written about this a little bit more in February, here:
http://www.gog.com/forum/general/games_finished_in_2013/post222 Then, Waxworks. An old game, therefor something can be forgiven, but it doesn't change the fact that like Last Express, this one was very confusing. Rarely did I know where to go and what to do. More about this here:
http://www.gog.com/forum/general/games_finished_in_2013/post34 (the last entry)
Silent Storm: Sentinels. Don't get me wrong, it's actually a really good game (in theory). But the reason it's on my list, is because one level has a bug that completely prevents progression from that point onward. A game that doesn't work is a very bad game in my book. Don't know if this is because of my computer or what, but GOG hasn't been able to solve the problem, despite me reporting it as early as last December. More about this here:
http://www.gog.com/forum/general/problem_with_silent_storm_sentinels (and the link within the link)
Temple of Elemental Evil: Difficulty is legendary, but even worse is the amount of bugs. Finished this once, then started a new playthrough with a new party since I now knew how to play the game better. However, at some point in the Temple, I ran into a bug that made the game crash every time I'd switch to a different floor, thus making the playthrough unwinnable. Again, not a bad game judging purely by how the gameplay is, but since it is possible to "break the game" due to a bug, it's a bad game.
I....think that's it. Bear in mind, there's still stuff on that shelf that's probably way worse than what I've listed here, but these are games I haven't played (some might say a game, say, AITD 3 is awful shit but I wouldn't know, I don't have any first-hand experience of the game because I haven't played it myself). But out of the four I listed, the worst is probably Waxworks. There's a certain novelty to it and I did play it all the way through (albeit with a walkthrough available at all times), but is it a good game? By gods, it is not, no matter how you look at it. Especially by today's standards, everything is done wrong in that game.