F.E.A.R. gets my vote too, excellent fps/spookathon game.
Killing Floor, funky solo, brilliant manic fps action in co-op or online random groups, runs suuuuuuuper smooth!
Call of Pripyat (
http://www.gog.com/game/stalker_call_of_pripyat ) is open world, mostly, but not so much so that it isn`t a constant battle to survive. (or any of the other S.T.A.L.K.E.R. series)
Crysis games are good too, Newer the version, more strain to your system (I`ve a 6850 & they work well, although third I don`t run maxed)