Lovely feature. And I'm impressed at the community for suggesting all the good games. :D
(Seriously, even Battle Bugs is on there. What more can one ask?)
No it isn't. Programmatically handling duplicates would actually require tacking on orders of complexity that I think is totally unnecessary.
For example, how do you handle the fact that games are published under different names in different countries? Or the fact that people may often misspell games? pkt-zer0 above made a suggestion for how to handle this which I think is absolutely ridiculous in that it just lumps on this crazy complexity.
That depends on how it is solved. A simple solution would be a little button for "mark as duplicate". You then get a little textbox where you can enter the url of the game it duplicates.
GOG staff/moderators/whatever can then read these submissions and (the easy solution) delete one of the duplicates and transfer the votes to the remaining one, or (slightly more advanced, but still pretty straightforward) let one be an alias for the other. So when you vote for X-Com: UFO Defense, it automatically adds the vote to UFO: Enemy Unknown, because they're the same game.
Of course automatically detecting duplicates would be a pain to do properly (but should still be done in the simple cases. People suggesting Fallout should get a little notice pointing out that it's already available, for example)
In fact, the 'add game' button should automatically perform a search and if a perfect match was found, use that instead. If similar names are found list them so you can see what similar games have been suggested already. Remember it doesn't have to be 100% guaranteed to eliminate duplicates. If it just makes it more obvious when you're submitting a duplicate, that's good enough. And if there's some mechanism to request a merge of duplicates after they've been created, we've pretty much got a win. None of this is rocket science to code.