AllenWake: Hey guys! I'm feeling pretty Evil this month so I want to play a really evil game...mainly when you play as the Bad guy. Don't know if there is really anything like that...but if you guys know any please let me know.
JudasIscariot: Dungeon Keeper :D
This, or DK2, or Overlord, or Overlord 2. They're all "popcorn" fun.
You can be a right bastard in Fable and Fable 2. Fable 3 too, but it's not as fun to be evil in that one.
Protoptype: there's nothing like consuming an innocent bystander so you can continue your quest for self centered revenge.
I hear Postal/Postal II are pretty psycho, but haven't yet played them.
I'm not sure that Killing Floor isn't meant to be the same kind of deluded fever dream that Postal is supposed to be.
Someone else said God or War series, I have to agree Kratos almost certainly lacks pure motives.
Star Wars The Force Unleashed is creepy good fun being a self centered jerk that does good only by serendipitous accident (don't play 2, unless you get it practically for free, then just buy the Endor DLC for 1 dollar and drop kick Ewoks).
From what I hear you can be a right douche to other actual players in DayZ.
Hope that sets you up for some wicked good fun:)