I can't really think of any instabuys nowadays, simply because I am not _that_ anxious to get to play some game I don't have already (and I already have more games than I could possibly play for the rest of my life, I think).
I'm interested to see and play many games, both old and new, just not very anxious to start playing them right away. Hence, I don't normally see the point of acquiring them right away, unless I fear I might not be able to do that in the future. Mass Effect 1-3, Dragon Age 1-2, KOTOR 1-2, Spec Ops: The Line etc. Sometime...
From GOG and such, I sometimes might instabuy without a discount to make a statement how much I approve that the publisher decided to release it (e.g. in GOG, or at least DRM-free). But these are rarer cases.
That reminds me: Space Pirates and Zombies might still be such a game, if the publisher either released it in GOG, or decided finally get rid of the DRM on their own site.