TCMU2009: Okay, so Crossfire isn't worth it with the 6000 series right now, but in two to three years I might find another cheap 6950 and get a performance boost that way.
That's right. Be sure to get a Crossfire-capable card (most, but not all, of them are) and a motherboard with a second PCI-Express x16 slot. Most better motherboards already have this. If the card comes with a "Crossfire bridge" (little ribbon cable that connects two cards across the top), be sure to save it for when you need it.
To minimize thermal problems, even with one 6950 (it runs pretty hot), get a large "full tower" case with plenty of ventilation and places you can attach large fans. Then don't worry about Crossfire until you get a chance to pick up a 6950 for little money.
TCMU2009: Okay, so Crossfire isn't worth it with the 6000 series right now, but in two to three years I might find another cheap 6950 and get a performance boost that way.
Phc7006: In theory, yes. But nothing guarantees that in 2-3 years you will be able to find a card that is fully compatible...
And, besides what has already been mentionned here about crossfire / sli ( modest increase in perf, large increase in power use ), be aware that multiple card solutions do cause problems related to heat management. Just check the thermal readings here :
http://www.hardware.fr/articles/813-5/temperatures.html. Even if the text is in French, the pics are pretty obvious ...
edit : as you can see, dual card systems create a halo of heat that contaminates the CPU and the RAM modules. This may cause loss of performance or even crashes if you don't compensate it with better cooling systems.
I'm suspicious of the quality of the cooling setup in that article. It shows the 6950 running much hotter, even in the single card configuration, than others report it running at full load. It should be running in the 80's, to 95C peak.
But your point is well taken. You want a GPU with a good cooler design, a case with lots of room and plenty of airflow, and ideally not much cross-flow between the GPU and CPU. (Those and the power supply are your three big heat producers. The power supply has its own ventilation. The GPU and CPU cooling should be arranged so that hot air goes directly out from the case.) This is true whether or not you are running Crossfired cards.