Kabuto: It's pretty much final. There's no benefit for GOG to do this. Customer satisfaction is nice but not at the expense of several sales.
cogadh: More than just no benefit to GOG, there is really no benefit to the publishers who see sites like GOG as a way to milk a little more money out of their old IPs, therefore they won't allow GOG to do it. I believe the GOG guys would not be opposed, at least philosophically, to doing something like this otherwise.
Even ignoring the logistics of it, I don't think they would. They'd still be providing an improved product, but not being paid for it. I have a feeling that their profits would go way down if all of a sudden people could buy a copy for $0.10 on ebay and get the compatibility updates from here for free to make it work.
They're marketed on being DRM free and compatible with modern OSes, most games they sell were DRM free or DRM light to begin with.