I think that the next big one is Atari (see The Witcher, Planescape re-release).
And then the next, Eidos (but there is Square to agree with it). I think we will never see Blizzard here, since they got their own store and there is SC2 and expansions coming out, and putting up Battle.net too. I doubt they'll release older games in the next 1,2 years, only if they try a different approach with their new system.
LucasArts, I highly doubt that it will be in GOG before mid-2010, if they ever do, and after releasing in other DD services too. They still have to release other games on Steam, the little ones like X-Wing series, Maniac Mansion, Grim Fandango...and maybe a X-Wing remake.
I hope SS1 and SS2 will be released close to the Thief series here on GOG. (I know, not an easy thing...) =D