tomimt: This isn't strictly true. While a good portion of DOS software does work under DosBox, there still is titles that it's not fully compatible with. It still runs probably around 90% of all titles, but even for the newest builds there's titles that won't run at all.
Out of curiosity, are these listed somewhere? EDIT: Ah ok, maybe this:
http://www.dosbox.com/comp_list.php?letter=broken I generally like DOSBox as I've had even better success rate running games on it than on my old MS-DOS retro-PC. Go figure, an emulator is more compatible with old games than a real MS-DOS PC...
EDIT2: Interesting that DOSBox "broken games" list, it includes games that I think even GOG has? Like:
Eye of the Beholder 3
Red Baron
Ishar 2
Tie Fighter
Aren't the GOG versions using DOSBox, and how did GOG get them working then?
Darling_Jimmy: Unless I'm mistaken, there was no DOS version of Myst. Sure you can install Windows 9x is DOSBox and then install Myst in that but ScummVM is much simpler in this case. The Curse of Monkey Island is another example that comes to mind.
Good point, ScummVM going beyond mere DOS games... Let's hope then ScummVM will add as many early Windows games as possible to their support list. :)