theirontable: I would like to just click one button to download it all
Install Galaxy.
Choose a game from your library.
Click on the Extras next to the install button.
Download the game.
In the downloads section of Galaxy, there is a folder to the far right. Click that and it will open the download location (Which will be Galaxy's default install folder\[Game Name]\!Downloads) In my case it is E:\Games\[Game Name]\!Downloads\
You can change the default install path on Galaxy by installing a game to your computer, or by going into the settins menu. (Gear at the top left, Settings, Installing/Updating)