FBReader for all your reading needs - smartphones aren't the best screen to read on, but since you'll always have it on you it's good to keep a few books on there.
Baen gives out free sci-fi and fantasy ebooks, as well as selling DRM-free ebooks directly so you can just download them and put them on your phone, no special apps needed. I really like Timothy Zahn and Sharon Lee/Steve Miller
Project Gutenberg has public domain classics.
MobileReads forum has a ton of information on where to get good legal ebooks.
Games:
LYNE
Threes
King of Dragon Pass
Buddy and Me
ScummVM lets you run adventure games on Android, so you can install that and copy over the data files. Adventure games work pretty well that way.
There have also been some PC games ported over like Shadowrun Returns and Knights of the Old Republic.
I use VLC Player for video and music, and ES File Explorer instead of the included file manager.